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Highly anti selective SN2′ additions of LiMe2Cu to chiral acyclic vinyloxiranes

✍ Scribed by James A. Marshall; Joseph D. Trometer; Bruce E. Blough; Thomas D. Crute

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 249 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82480-6

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Additions of LiMezCu to acyclic vinyloxiranes 4, 5, 6, and 7 proceed predominately anti &2' to afford the (E)-allylic alcohol products. The SN~' addition of organocopper reagents to vinyloxiranes is a well established synthetic route to allylic alcohols. However, except for the initial observation

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## Abstract For Abstract see ChemInform Abstract in Full Text.