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Highly Active Titanium-Based Olefin Polymerization Catalysts Supported by Bidentate Phenoxyamide Ligands

✍ Scribed by Oakes, Daniel C. H.; Gibson, Vernon C.; White, Andrew J. P.; Williams, David J.

Book ID
126211907
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
46 KB
Volume
45
Category
Article
ISSN
0020-1669

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Titanium Complexes Stabilized by a Sulfu
Titanium Complexes Stabilized by a Sulfur-Bridged Chelating Bis(aryloxo) Ligand as Active Catalysts for Olefin Polymerization
✍ Zofia Janas; Lucjan B. Jerzykiewicz; Katarzyna Przybylak; Piotr Sobota; Krzyszto 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

## Abstract The mixed‐ligand complexes [Ti~2~(μ‐OR)~2~(OR)~2~(κ^3^‐tbop)~2~] (1a) for R = Me and (1b) R = Et were prepared by the reaction of Ti(OR)~4~ and H~2~tbop {H~2~tbop = 2,2′‐thiobis[4‐(1,1,3,3‐tetramethylbutyl)phenol]} in methanol. Treatment of 1a and 1b with AlMe~3~ led to the substitution