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Highly Active Catalyst for the Heterogeneous Suzuki−Miyaura Reaction: Assembled Complex of Palladium and Non-Cross-Linked Amphiphilic Polymer

✍ Scribed by Yamada, Yoichi M. A.; Takeda, Koji; Takahashi, Hideyo; Ikegami, Shiro

Book ID: 126952732
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 229 KB
Volume: 68
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo034354v

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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A newly assembled insoluble catalyst 1b composed of palladium and non-cross-linked amphiphilic polymer was developed. It was named PdAS-V: a supramolecular complex of (NH 4 ) 2 PdCl 4 (2) and poly[(N-isopropyla6 crylamide) 5 -co-(4-diphenyls6 tyrylphosphine)] (3b). The use of 8.0×10 -7 -5.0×10 -5 mo