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Highly Active and Selective Platinum(0)-Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins

✍ Scribed by István E. Markó; Sébastien Stérin; Olivier Buisine; Guillaume Berthon; Guillaume Michaud; Bernard Tinant; Jean-Paul Declercq

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 206 KB
Volume: 346
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200404048

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✦ Synopsis

Abstract

Readily available N‐heterocyclic platinum‐carbene complexes 1 are highly efficient catalysts for the regioselective hydrosilylation of alkenes. These novel organometallics tolerate a wide range of functional and protecting groups, can be stored for prolonged periods of time and are particularly active (TON>10^6^).

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