## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Highlights of the Chemistry of Enantiomerically Pure Aziridine-2-carboxylates
β Scribed by Won Koo Lee; Hyun-Joon Ha
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 49 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract Enantiomerically pure __cis__β and __trans__β1__H__βaziridineβcarboxylic acid derivatives 2a, b and 3a, b have been prepared by asymmetric Michaelβtype addition of ammonia to chiral acrylates 1a, b with high __syn__ selectivity. The title compounds were obtained from the diols 8a, b by
Synthesis of Enantiomerically Pure Vinylcyclopropanes by S N 2' Allylic Carboxylate Displacements. -The readily available optically pure lactones (I) or (XIII) undergo palladium-catalyzed displacement by a variety of stabilized carbon, oxygen, and nitrogen nucleophiles to afford as major S N 2' prod