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Higher dimensional networks of Mn(II) azide/cyanate using flexible N-donor ligands: Synthesis, crystal structure and magnetic properties

✍ Scribed by Ananta Kumar Ghosh; Debajyoti Ghoshal; Joan Ribas; Ennio Zangrando; Nirmalendu Ray Chaudhuri


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
655 KB
Volume
796
Category
Article
ISSN
0022-2860

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Two new polynuclear complexes of Cu II , [Cu 2 (fum)(Β΅-OH)(bpy) 2 (H 2 O)](NO 3 )β€’2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]β€’2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.