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High-Yielding Rotaxane Synthesis with an Anion Template

✍ Scribed by Gosia M. Hübner; Jens Gläser; Christian Seel; Fritz Vögtle


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
122 KB
Volume
38
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


High Yielding Template-Directed Synthese
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Three dumbbell-shaped compounds incorporating terminal chains of the templates influences the efficiencies of the template-directed syntheses. Rotaxane formation occurs only triisopropylsilyl stoppers, connected to a central 1,5dioxynaphthalene recognition site by [-CH 2 CH 2 O-] n spacers if n Ͼ 1

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Non-ionic template effects [1] proved to be a successful concept to synthesize supramolecular architectures [2], especially hydrogen bond-mediated catenane [3] and rotaxane [4] formation [5]. In the beginning aromatic diacid dichlorides were believed to be the guests to fit into tetralactame macroc