✦ LIBER ✦

High-yield γ-ray-induced polymerization of bis-2-acetoacetoxyethyl methacrylate copper. II.

✍ Scribed by M. Bertolin; M. Zecca; G. Favero; G. Palma; S. Lora; D. Ajo; B. Corain

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 197 KB
Volume: 65
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19970912)65:11<2201::aid-app17>3.0.co;2-5

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✦ Synopsis

The copper (II) acrylic monomer Cu(aaem) 2 (aaem Å 2-acetoacetoxyethyl methacrylate) undergoes high-yield g-ray copolymerization with dimethylacrylamide, styrene, and hydroxoethyl methacrylate in the presence of methylene bisacrylamide as crosslinking agent in dimethylformamide. The metalloorganic copolymers are fully characterized. Polymer-protected Cu(II) results in being extremely stable toward a number of reducing agents in different media.