High-yield synthesis of the smaller closo-carboranes dicarbapentaborane(5), dicarbahexaborane(6), and dicarbaheptaborane(7)

Oxidative and cluster Aufbau reactions o

Oxidative and cluster Aufbau reactions of nido-6-metalladeaboranes induced by Lewis bases such as SMe2: high-yield formation of [1-(?6-C6Me6)-isocloso-1-RuB9H9] and the molecular structure of the Rh-commo-(isonido-eleven-vertex)-(closo-ten-vertex)conjuncto species [(?5-C5Me5)RhB9(SMe2)H10RhB9H7(SMe2)2]

✍ Ditzel, Evert J.; Fontaine, Xavier L. R.; Greenwood, Norman N.; Kennedy, John D. 📂 Article 📅 1989 🏛 The Royal Society of Chemistry 🌐 English ⚖ 315 KB