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High Yield Synthesis, Molecular Structure, and Reactions of the 16-Electron Norbornadiene Complex, [WI2(CO)2(nbd)]

✍ Scribed by Paul K. Baker; Michael G. B. Drew; Margaret M. Meehan; Jan Müller


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
75 KB
Volume
628
Category
Article
ISSN
0372-7874

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The Chemistry of 1,3,5-Triazacyclohexane
✍ Köhn, Randolf D. ;Kociok-Köhn, Gabriele ;Haufe, Matthias 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 301 KB

## Abstract The reaction of __N,N′,N′′__‐trimethyl‐1,3,5‐triazacyclohexane chromium trichloride ((Me~3~TAC)CrCl~3~, 1) with LiN(SiMe~3~)~2~ or NaN(SiMe~3~)~2~ in petroleum ether yields nearly quantitatively [Cr{N(SiMe~3~)~2~}~3~] (2) with loss of the Me~3~TAC ligand. Compound 2 could be crystallize