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High-Yield Molecular Borazine Precursors for Si—B—N—C Ceramics.

✍ Scribed by Joerg Haberecht; Frank Krumeich; Hansjoerg Gruetzmacher; Reinhard Nesper


Publisher
John Wiley and Sons
Year
2004
Weight
63 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract A new kind of polyorganozircosilazane as a Si/Zr/C/N‐based ceramic precursor was synthesized from the condensation reaction of hexamethylcyclotrisilazane lithium salts and zirconium tetrachloride. The pyrolysis of the precursor was carried out at 800°C under nitrogen. The results indica