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High-vacuum pyrolysis of 1,1,1-trifluoro-2-bromo-2-chloroethane. IR spectrum of 1,1,1-trifluoro-2-chloroethyl radical in an argon matrix

✍ Scribed by E. G. Baskir; V. A. Korolev; O. M. Nefedov


Book ID
105595181
Publisher
Springer
Year
1998
Tongue
English
Weight
335 KB
Volume
47
Category
Article
ISSN
1573-9171

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## Abstract The thermal decomposition of 1,1,1‐trifluoro‐2‐chloroethane has been investigated in the single‐pulse shock tube between 1120Β° and 1300deg;K at total reflected shock pressures from ∼2610 to 3350 torr. Under these conditions, the major reaction is the Ξ±,α‐elimination of hydrogen chloride