High-Throughput Synthesis of New Ni(II), Pd(II), and Co(II) Catalysts and Polymerization of Norbornene Utilizing the Self-Made Parallel Polymerization Reactor System
✍ Scribed by Hyun Yong Cho; Dae Sik Hong; Dong Wook Jeong; Young-Dae Gong; Seong Ihl Woo
- Book ID
- 102492464
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 202 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: We report the development of new Ni(II), Pd(II), and Co(II) catalysts containing ligands of pyrazolylpyridine derivatives by combinatorial and high‐throughput synthesis technology. Vinyl type polynorbornene was polymerized utilizing the self‐made parallel polymerization reactor system. The Ni(II) catalyst 1 has a polymerization activity of 266.7 kg~polymer~ · mol~cat~^−1^ · h^−1^. We introduce a fast way to conduct catalyst synthesis and high‐throughput screening for polymerization.
The self‐made parallel polymerization reactor system.
magnified imageThe self‐made parallel polymerization reactor system.