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High temperature stable CH3O-terminated poly(diphenyl/dimethyl)- and poly(diphenyl/3,3,3-trifluoropropylmethyl)siloxane copolymer stationary phases for capillary gas chromatography

✍ Scribed by Wolfgang Blum; Reiner Aichholz

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
430 KB
Volume
5
Category
Article
ISSN
1040-7685

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✦ Synopsis

Abstract

The preparation of two new medium polar CH~3~O‐terminated 50% diphenyl substituted polysiloxane phases by means of a one step condensation of bis(dimethylamino)alkylsilanes and diphenysilanediol is reported. Both phases can be used up to temperatures of 420°C. The unusual route of synthesis offers an easy and reliable way to prepare a variety of tailor‐made high temperature stable polysiloxane phases.

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