## Abstract Very high lateral ionic conductivities in epitaxial cubic yttria‐stabilized zirconia (YSZ) synthesized on single‐crystal SrTiO~3~ and MgO substrates by reactive direct current magnetron sputtering are reported. Superionic conductivities (i.e., ionic conductivities of the order ∼1 Ω^−1^c
High-temperature stability in yttria-stabilized zirconia
✍ Scribed by Mitsue Ogawa
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 675 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1099-2871
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✦ Synopsis
Abstract
Yttria‐stabilized zirconia has been studied as a candidate standard reference material for the determination of thermal properties. This study evaluated the high‐temperature stability, which is important for yttria‐stabilized zirconia to be used for a standard reference material, using a common material of fine ceramics, Referceram ZR1 (zirconia). The high‐temperature stability was evaluated by measuring the change in the thermal diffusivity before and after heat treatment at temperatures between 200 ^°^C and 1500 ^°^C. No change in the thermal diffusivity was observed when the samples were treated at temperatures equal to or below 900 ^°^C. However, it was revealed that the changes in the thermal diffusivity were caused by the transformation and separation of the crystal phase and the cracks that occur at grain boundaries when the samples were treated at temperatures equal to or above 1000 ^°^C. From these results, we confirmed that Referceram ZR1 is sufficiently stable for use as a reference material at temperatures equal to or below 900 ^°^C. © 2008 Wiley Periodicals, Inc. Heat Trans Asian Res, 37(2): 57–67, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20193
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Heat capacities of pure zirconia ZrO 2 and 7.76•10 -2 mole fraction yttria-stabilized zirconia (ZrO 2 ) 0.9224 (Y 2 O 3 ) 7.76•10 -2 were measured by adiabatic calorimetry at temperatures between 13 K and 300 K. The results were compared and analysed from the standpoint of the effects of yttria dopi