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High Temperature Reaction Rate for H + O2 = OH + O and OH + H2 = H2O + H

โœ Scribed by Frank, P.; Just, Th.


Book ID
120833685
Publisher
Wiley (John Wiley & Sons)
Year
1985
Tongue
English
Weight
700 KB
Volume
89
Category
Article
ISSN
0372-8323

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The nascent state distributions of OH produced in the reaction H+H20+0H+H2 were probed by fast atom-laser-induced fluorescence experiments. Translationally hot H atoms were formed by photolysis of HI at 250 and 270 nm leading to H+HrO c.m. collision energies E of 176 and 143 kJ/mol. With a calibrat

Vibrational rate enhancement in the reac
โœ R Zellner; W Steinert ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 317 KB

The rate constant for the reaction between OH and vibrationally excited H2, OH + H 2 (v = 1) ~ H20 + H, has been measured directly at 298 K. kol is found to be (7.5 -+ 3) X 10 -13 cma/molecule s, corresponding to a vibrational rate enhancement ofkol/koo = (1.2 -+ 0.4) X 102.