✦ LIBER ✦

High temperature rate coefficient measurements of CO + O chemiluminescence

✍ Scribed by M. Slack; A. Grillo

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 488 KB
Volume: 59
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(85)90024-0

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✦ Synopsis

Spectral intensities from the chemiluminescent reaction CO + O --* CO2 + hv have been measured in the range 2600-7000 /k from reacting mixtures of H2-O2-CO-CO2-argon, shock heated in a shock tube to temperatures of 1300 and 2700K. Integrals of the photon production rate yield an overall rate coefficient -to = 6.8 ( +_ 0.6) x 105 exp(-1960/73 cm 3 mole-~ s-~. Extrapolated to 300K, this rate coefficient is in excellent agreement with the room temperature measurements of Pravilov.

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