✦ LIBER ✦

High temperature pyrolysis of 1,5-cyclooctadiene and 4-vinylcyclohexene in shock waves

✍ Scribed by Yoshiaki Hidaka; Natsuhiko Ninomiya; Hidekazu Oshita; Hiroyuki Kawano; Tohru Koike

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 298 KB
Volume: 25
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550251208

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✦ Synopsis

Abstract

1,5‐cyclooctadiene or 4‐vinylcyclohexene mixture diluted with argon was heated to temperatures in the range 880–1230 K behind reflected shock waves. Profiles of IR‐laser absorption were measured at 3.39 μm. From these profiles, rate constants k~1~ and k~2~ for the decyclization reactions 1,5‐cyclooctadiene → biradical and 4‐vinylcyclohexene → biradical were evaluated as k~1~ = 5.2 × 10^14^ exp(−48.3 __k__cal/RT) s^−1^ and k~2~ = 3.5 × 10^14^ exp(−55.3 __k__cal/RT) s^−1^, respectively. © 1993 John Wiley & Sons, Inc.

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