High-Temperature Measurements and a Theoretical Study of the Reaction of OH with 1,3-Butadiene
✍ Scribed by Vasu, Subith S.; Zádor, Judit; Davidson, David F.; Hanson, Ronald K.; Golden, David M.; Miller, James A.
- Book ID
- 120810554
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 487 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Low pressure (4.67 kPa) CiI,/02/Ar flames were seeaed with approximately 5300 ppm NH,. The concentration profiles of stable and radical species in lean (6 = 0.92) and rich (r#~ = 1.13) flames were determined by molecular beam sampling mass spectrometry. Temperature profiles in these flames were meas
Mixtures of NH, and N,O dilute in Ar were heated behind incident shock waves in the temperature range 1750-2060 K. A cw ring dye laser, tuned to the center of an OH absorption line in the ultraviolet, was used to monitor OH concentration profiles by absorption spectroscopy. Infrared emission was use
## Abstract The reaction between methyl and hydroxyl radicals has been studied in reflected shock wave experiments using narrow‐linewidth OH laser absorption. OH radicals were generated by the rapid thermal decomposition of tert‐butyl hydroperoxide. Two different species were used as CH~3~ radical