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High-Temperature Lithium Mobility in α-LiZr2(PO4)3 NASICON by Neutron Diffraction.

✍ Scribed by M. Catti; A. Comotti; S. Di Blas


Publisher
John Wiley and Sons
Year
2003
Weight
62 KB
Volume
34
Category
Article
ISSN
0931-7597

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Neutron di4raction pro5les at high resolution (HRPD, ISIS Facility, U.K.) were collected on powder samples of LiZr2(PO4)3 at 203C ( phase, monoclinic P21/n, Z ‫؍‬ 4; a ‫؍‬ 8.81277(4), b ‫؍‬ 8.94520(5), c ‫؍‬ 12.37540(6) A s , ‫؍‬ 90.801(1)3) and at 3503C ( phase, orthorhombic Pbna, Z ‫؍‬ 4; a ‫؍‬ 8.

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The lithium conductors Li 2 FeTi(PO 4 ) 3 and Li 2 FeZr(PO 4 ) 3 , synthesized by solid-state reaction and characterized by X-ray powder di4ractometry, were studied structurally at room temperature by neutron powder di4raction at high resolution (HRPD, ISIS Facility, U.K.). By trial-and-error and Ri