The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =
High-temperature kinetics of the reaction CN + CO2
β Scribed by D. Lindackers; M. Burmeister; P. Roth
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 492 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0010-2180
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## Abstract The rate coefficient of the reaction has been determined in the temperature range of 2700β3500 K using a shock tube technique. C~2~N~2~ο£ΏH~2~ο£ΏAr mixtures were heated behind incident shock waves and the earlyβtime CN history was monitored using broadβband absorption spectroscopy. The ra
The rate coefficient of the reaction H + CO z ~ CO + OH (1) was measured using OH concentration measurements in shock-heated N20-H2-CO 2 mixtures and through the inhibiting effect of CO 2 on methane ignition. For 2170 < T < 3150 K the two methods give concordant results and imply k I = 2.0 Γ 1014exp