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High spin metastable state relaxation of spin-crossover solids driven by white noise

✍ Scribed by Iurii V. Gudyma; Artur Iu. Maksymov


Book ID
108191795
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
303 KB
Volume
72
Category
Article
ISSN
0022-3697

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The high-spin β†’ low-spin relaxation in spin-crossover compounds can be described as non-adiabatic multi-phonon process in the strong coupling limit, in which the low-temperature tunnelling rate increases exponentially with the zero-point energy difference between the two states. Based on the hypothe