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High spin-low spin crossover in Co(II) complexes with tris(2-diphenylphosphinoethyl)amine (NP3) by application of high external pressures

✍ Scribed by John R. Ferraro; Louis J. Basile; Luigi Sacconi


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
185 KB
Volume
35
Category
Article
ISSN
0020-1693

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✦ Synopsis


Details of the syntheses of the five-coordinate Co(I1) complexes with tris(2diphenylphosphinoethyl)amine (NP,) have been discussed [9].

Spectroscopic Studies

Visible and near infrared spectra were obtained with a Cary 14R spectrophotometer. The measurements were made in a DAC interfaced with a beam condenser [IO].

FIR measurements were made on a Beckman IR-11 using a 6X beam condenser [ 1 l] , and a Beckman Model 4260 using a 4X beam condenser [ 121.