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High-spin and low-spin iron(ii) complexes with facially-coordinated borohydride ligands

✍ Scribed by Mehn, Mark P. ;Brown, Steven D. ;Paine, Tapan K. ;Brennessel, William W. ;Cramer, Christopher J. ;Peters, Jonas C. ;Que, Jr., Lawrence

Book ID
120287907
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
202 KB
Volume
10
Category
Article
ISSN
1477-9226

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Low spin-high spin planar Ni(II) complex
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✍ Hans Josef Mink; Hans-Herbert Schmidtke πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 449 KB

The bis(di-tert-butylphosphinic-N-tert-pentyl-amidato-N, O) Ni(II) complex is planar and has a spin triplet of low energy (300-400 cm-l) close to the singlet ground state. The measured absorption spectrum exhibits two ligand field bands in the near-infrared and some other features in the visible whi