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High Solids Vinyl Acetate Polymers from Miniemulsion Polymerization

✍ Scribed by Graillat, Christian; Guyot, Alain


Book ID
127393917
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
70 KB
Volume
36
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


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The stability of vinyl acetate miniemulsions employing polyvinyl alcohol (PVOH) as the surfactant, and hexadecane and/or various polymers as the cosurfactant, were studied. Shelf lives (to phase separation) and monomer droplet sizes were measured. The results indicate that it is possible to prepare

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## Abstract **Summary:** A series of butyl acrylate/vinyl acetate miniemulsions were investigated. Two procedures were used to prepare the miniemulsions: one in which the monomers were mixed together, sonicated, and polymerized, and the other, in which the individual monomers were sonicated prior t

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## Abstract **Summary:** The MADIX/RAFT mechanism, employing a xanthate as the reversible chain‐transfer agent, has been shown to facilitate the living radical polymerization of vinyl acetate in miniemulsion. Methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) successfully mediated the polymerizati