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High-Resolution Study of the X22Π1/2 → X12Π3/2 Fine-Structure Transitions of 130TeF and 130Te35Cl

✍ Scribed by K. Ziebarth; K.D. Setzer; E.H. Fink

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
491 KB
Volume
173
Category
Article
ISSN
0022-2852

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✦ Synopsis

The near-infrared emission spectra of the (X_{2}{ }^{2} \Pi_{1 / 2} \rightarrow X_{1}{ }^{2} \Pi_{3 / 2}) fine-structure transitions of ({ }^{130} \mathrm{TeF}) and ({ }^{130} \mathrm{Te}{ }^{35} \mathrm{Cl}) have been investigated by high-resolution Fourier-transform spectrometry. The radicals were generated and excited in a fast-flow system by reaction of (\mathrm{TeH} / \mathrm{TeH}{2}) with (\mathrm{F}{2}) or (\mathrm{Cl}{2}). Analyses of the spectra have yielded the first accurate molecular constants for the ({ }^{2} \Pi{i}, v) (=0) ground state of both molecules. (1) 1995 Academic Press, Inc.

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