Analysis of the high-resolution Fourier transform spectra of the D 2 O first decade was carried out in the framework of the Hamiltonian model which took into account resonance interactions between the seven states, (300), ( 201), ( 102), ( 003), ( 220), (121), and (022). Assigned from the experiment
High-Resolution Study of Strongly Interacting Vibrational Bands of HDO in the Region 7600–8100 cm−1
✍ Scribed by Shui-Ming Hu; O.N. Ulenikov; G.A. Onopenko; E.S. Bekhtereva; Sheng-Gui He; Xiang-Huai Wang; Hai Lin; Qing-Shi Zhu
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 160 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 7600 -8100 cm Ϫ1 where the weak vibration-rotation bands 3 1 and 1 ϩ 2 ϩ 3 are located. Because of the presence of strong local resonance interactions, transitions belonging to the 3 2 ϩ 3 and 6 2 bands were assigned as well. Spectroscopic parameters of all four bands were estimated, which reproduce initial line positions with accuracy close to experimental uncertainties.
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