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High-Resolution Spectroscopy and Analysis of the ν3 and ν4 Fundamentals of Monoisotopic 70GeF4

✍ Scribed by V. Boudon; H. Bürger; E.B. Mkadmi

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
310 KB
Volume
206
Category
Article
ISSN
0022-2852

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✦ Synopsis

The first high-resolution study on germanium tetrafluoride is reported. We used a monoisotopic sample of 70 GeF 4 . The FTIR spectra of the two infrared active fundamentals, namely the ν 4 (bending) and ν 3 (stretching) modes, were recorded at a temperature of ca. 210 K and a resolution (1/maximum optical path difference) of 0.0031 and 0.0023 cm -1 , respectively. These spectra were analyzed using the STDS software developed in Dijon. In both cases, we obtained a fit with a root mean square better than 1 × 10 -3 cm -1 . Both bands show very regular structures with no detectable perturbation.

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