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High-resolution solid-state 29Si NMR of polymorphs of Ca2SiO4

✍ Scribed by A.-R. Grimmer; F. von Lampe; M. Mägi; E. Lippmaa

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
337 KB
Volume
15
Category
Article
ISSN
0008-8846

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✦ Synopsis

High-resolution solid-state 29Si NMR spectra of four (Y, 8, e~ and e) polymorphs of Ca2SiO 4 have been measured. The isotropic silicon 29Si chemical shifts lie between -73.5 and -70.1 ppm, and increasing coordination number of calcium leads to low-field 29Si shifts. The 29Si shifts in combination with the linewidth information allow to identify the C2S phases by 29Si NMR.

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