𝔖 Bobbio Scriptorium
✦   LIBER   ✦

High-Resolution Photoacoustic Study of the ν1 + 3ν3 Band System of Acetylene with a Titanium:Sapphire Ring Laser

✍ Scribed by X.W. Zhan; L. Halonen

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
319 KB
Volume
160
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The (v_{1}+3 v_{3}) band system of natural acetylene has been recorded with Doppler-limited resolution using a titanium:sapphire ring laser together with a intracavity photoacoustic detection method. The (v_{1}+3 \nu_{3}) band appears by far as the strongest feature in the spectrum but there are many weaker bands nearby. In the wavenumber region (12450-12800 \mathrm{~cm}^{-1}) we have analyzed rotationally 19 overtone and hot bands belonging to the ({ }^{12} \mathrm{C}{2} \mathrm{H}{2}) species and 2 overtone bands belonging to ({ }^{12} \mathrm{C}^{13} \mathrm{CH}_{2}). Many of the observed bands show perturbations. Some of these have been analyzed successfully with Coriolis or Fermi resonance models. (C) 1993 Academic Press, inc.

📜 SIMILAR VOLUMES

High-Resolution Laser Photoacoustic Spec
High-Resolution Laser Photoacoustic Spectroscopy of HSiF3: The 5ν1 and 6ν1 Overtone Bands
✍ M. Lecoutre; T.R. Huet; E.B. Mkadmi; H. Bürger 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 151 KB

A spectrum of HSiF 3 has been recorded at room temperature with a gas pressure of 20 -50 Torr in the near-infrared region. A laser photoacoustic spectrometer consisting of a longitudinal resonant cell coupled to a titanium:sapphire ring laser was employed. The 5 1 and 6 1 overtone bands of H 28 SiF

H280Se: High-Resolution Study of the 2ν1
H280Se: High-Resolution Study of the 2ν1 + ν2, ν1 + ν2 + ν3, 3ν1, 2ν1 + ν3 and ν1 + 2ν3 Bands
✍ J.M. Flaud; C. Camypeyret; P. Arcas; H. Burger; H. Willner 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 449 KB

Using high-resolution Fourier transform spectra of monoisotopic \(\mathrm{H}_{2}{ }^{80} \mathrm{Se}\) recorded in the 1.8 and \(1.55-\mu \mathrm{m}\) regions. an extensive analysis of the \(2 \nu_{1}+\nu_{2}, \nu_{1}+\nu_{2}+\nu_{3}, 3 \nu_{1}, 2 \nu_{1}+\nu_{3}\), and \(\nu_{1}+\) \(2 v_{3}\) band

High-Resolution FTIR Study of the (ν3+ ν
High-Resolution FTIR Study of the (ν3+ ν4, ν1+ ν4) Interacting System of Rovibrational Bands of PF3Between 1100 and 1300 cm−1
✍ N.Ben Sari-Zizi; H Najib; R Sebihi; P Pracna 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 363 KB

With a resolution of 4.4 1 10 03 cm 01 , we were able to identify in this range the very weak n 2 / 2n 0 4 (A 1 ) component near 1180 cm 01 , the n 3 / n 4 band around 1205 cm 01 with its (A 1 / A 2 ) and E very intermixed components, and the n 1 / n 4 (E) band centered at 1238 cm 01 . Three thousan

High-Resolution Photoacoustic Study of A
High-Resolution Photoacoustic Study of Acetylene Between 11 500 and 11 900 cm−1 Using a Titanium:Sapphire Ring Laser
✍ X.W. Zhan; O. Vaittinen; L. Halonen 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 416 KB

A titanium:sapphire ring laser has been used in a high-resolution intracavity photoacoustic study of a natural sample of acetylene in the infrared region \(11480-11880 \mathrm{~cm}^{-1}\). The spectra show a dense structure of vibration-rotation overtone bands of \(\mathrm{H}^{12} \mathrm{C}^{12} \m

High-Resolution Laser Spectroscopy of th
High-Resolution Laser Spectroscopy of the A3Π1←X1Σ+ System of IBr with a Titanium:Sapphire Ring Laser
✍ Tokio Yukiya; Nobuo Nishimiya; Masao Suzuki 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 453 KB

The vibrotational absorption spectra of the A ← X electronic transition of I 79/81 Br were measured in the 11 330-to 13 220-cm -1 region using a Ti:sapphire ring laser. The P-, Q-, and R-branch lines of the rotational states from J = 10 to 100 belonging to the v ← v = (3∼20) ← (1∼6) bands were assig