High-resolution laser-induced fluorescence study of a cage molecule, 1,4-diazabicyclo [2,2,2] octane, DABCO
β Scribed by D. Consalvo; M. Drabbels; G. Berden; W. Leo Meerts; D.H. Parker; J. Reuss
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 936 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0301-0104
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Picosecond and nanosecond dynamics of the ion pair produced by the electron transfer reaction between the triplet state benzophenone ('BP\*) and 1,4-diazabicyclo[ 2.2.2loctane (DABCO) wasinvestigated by means oftransientabsorption spectroscopy and laser-induced photoconductivity measurement. It has
## Abstract Pulsed laser photolysis/vacuum ultraviolet laserβinduced fluorescence techniques were used to measure rate coefficients for Cl atom reactions with a series of fluoroalkenes (C~x~F~2x+1~CHο£ΎCH~2~, __x__ = 1,2,4,6,8) in 6β10 Torr of CF~4~ diluent at 295 Β± 2 K. Rate coefficients (units of 1