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High-Resolution FTIR Spectrum of the CF Radical

✍ Scribed by T. Nakanaga; F. Ito; H. Takeo

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 382 KB
Volume: 165
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1994.1112

No coin nor oath required. For personal study only.

✦ Synopsis

The high-resolution infrared absorption spectrum of the fundamental band of CF radical has been measured with an FTIR spectrometer. Reliable molecular constants of the vibrationally excited state have been obtained. The vibrational transition dipole moment has been estimated, via Herman-Wallis theory, to be (\mu_{10}=-0.14(7) \mathrm{D}) from the analysis of the intensity distribution of the vibration-rotation lines. The sign of the transition dipole moment has been found to be opposite to that of the permanent dipole moment. (c. 1994 Academic Press, Inc.

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