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High-Resolution FTIR Spectrum and Rotational Structure of the ν8Band of Methylene Chloride

✍ Scribed by W.F. Wang; T.L. Tan; B.L. Tan; P.P. Ong


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
210 KB
Volume
175
Category
Article
ISSN
0022-2852

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✦ Synopsis


The high-resolution Fourier-transform infrared spectrum of the n 8 band of methylene chloride (CH 2 Cl 2 ) was measured in the range 1230-1305 cm 01 . The band shows the typical A-type contour of an asymmetric-top molecule. A rovibrational structure analysis of the spectrum provided a set of accurate upper state constants up to some quartic centrifugal distortion constants which could reliably reproduce the observed spectrum. The absorption lines of the two isotopomers CH 2 35 Cl 2 and CH 2 35 Cl 37 Cl were identified. A total of 1314 transitions for CH 2 35 Cl 2 and 595 transitions for CH 2 35 Cl 37 Cl were assigned and fitted with an isotopic band center shift of about 0.035 cm 01 for this CH 2 wagging fundamental mode. The measurement on the integrated band intensity was also performed and gave a value of (1.57 { 0.08) 1 10 017 cm/ molecule, taking into account the contribution from the hot bands in this region. Comparison between the observed and calculated band intensity gave an estimate of the dipole transition moment component along the a-axis at a value of Ém a É Å 0.218 D.


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