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High-resolution Fourier transform spectrum and rovibrational analysis of the coriolis coupled ν3 and ν6 fundamentals of H3SiF near 800 cm−1

✍ Scribed by H Bürger; P Schulz; J Kauppinen

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
818 KB
Volume
119
Category
Article
ISSN
0022-2852

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The \(\nu_{2}\left(A_{1}, 710.157 \mathrm{~cm}^{-1}\right)\) and \(\nu_{5}\left(E, 701.717 \mathrm{~cm}^{-1}\right)\) fundamental bands of \(\mathrm{D}_{3}{ }^{28} \mathrm{SiF}\) have been studied by FTIR spectroscopy with a resolution of \(2.4 \times 10^{-3} \mathrm{~cm}^{-1}\). We assigned 1648 li

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The high-resolution spectra of the vibration-rotational bands \(\nu_{3}\) and \(\nu_{6}\) of gaseous \(\mathrm{D}_{3}{ }^{70} \mathrm{GeH}\) have been measured in the region \(395-890 \mathrm{~cm}^{-1}\) with a resolution of \(0.0035 \mathrm{~cm}^{-1}\). A variational approach has been applied to th

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A high-resolution FT infrared spectrum of H 3 SiF (resolution 0.0024 cm Ϫ1 ) in the region 620 -1130 cm Ϫ1 was measured and used to analyze the fundamental bands 2 ( A 1 ), 990.851 cm Ϫ1 ; 3 ( A 1 ), 875.011 cm Ϫ1 ; 5 (E), 962.213 cm Ϫ1 ; and 6 (E), 729.528 cm Ϫ1 . A total number of 7241 transition