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High resolution 13C NMR in undoped cis- and trans-polyacetylene

✍ Scribed by M. Mehring; H. Weber; W. Müller; G. Wegner


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
260 KB
Volume
45
Category
Article
ISSN
0038-1098

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13C high-resolution NMR study of undoped
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13C NMR spectra of undoped polyacetylene, (CH),, have been measured. The existence of 3.4 mol% methyiene moieties as defects in the (CH), chains has been observed in t~ans-(CH)~. Measurements of partially cis-to-trans isomerized (CH), suggest the existence of isolated cis regions.

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Before and after cis-trans isomerization, the observed 13 C-NMR chemical shifts of poly(phenylacetylene) (PPA) in the solid state were investigated on the basis of 13 C-NMR chemical shift calculations within AM1 for the cis-transoidal and deflected trans-transoidal forms. Two 13 C-resonance peaks in