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High-quality polyene prepared by liquid/solid two-phase dehydrochlorination of poly(vinyl chloride)

✍ Scribed by L.-T. Qu; G.-Q. Shi; F.-E. Chen; J.-X. Zhang; M.-X. Fu; S.-Q. Sun

Book ID: 117539341
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 249 KB
Volume: 135-136
Category: Article
ISSN: 0379-6779
DOI: 10.1016/s0379-6779(02)00629-x

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## Abstract The reaction of poly(vinyl chloride) powder with aqueous sodium hydroxide solution in the presence of quaternary ammonium or phosphonium halides yielded dehydrochlorinated products of conjugated polyene structure. The reaction was discussed in terms of a phase transfer catalytic mechani