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High-quality hydrogen from the catalyzed decomposition of formic acid by Pd–Au/C and Pd–Ag/C

✍ Scribed by Zhou, Xiaochun; Huang, Yunjie; Xing, Wei; Liu, Changpeng; Liao, Jianhui; Lu, Tianhong

Book ID
115511336
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
521 KB
Volume
30
Category
Article
ISSN
1359-7345

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✍ Kazuyuki Hattori; Hironao Sajiki; Kosaku Hirota * 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 166 KB

While the frequent and unexpected loss of the TBDMS protective group of a variety of hydroxylic functions was demonstrated under neutral and mild hydrogenation conditions using 10% Pd/C, the undesirable problem was perfectly overcome by using a 10% Pd/C-ethylenediamine complex catalyst.