## Abstract The radical‐molecule reaction mechanism of CHCl~2~ and CCl~3~ with NO~2~ have been explored theoretically at the B3LYP/6‐311G(d,p) and MC‐QCISD (single‐point) levels. For the singlet potential energy surface (PES) of CHCl~2~ + NO~2~ reaction, the association of CHCl~2~ with NO~2~ was fo
High-Pressure Studies of Radical−Solvent Molecule Interactions in the CCl 3 and Bromine Combination Reactions of CCl 3
✍ Scribed by Oum, Kawon; Luther, Klaus; Troe, Jürgen
- Book ID
- 126141030
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 158 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Rate coefficients, __k__, and ClO radical product yields, __Y__, for the gas‐phase reaction of O(^1^D) with CClF~2~CCl~2~F (CFC‐113) (__k__~2~), CCl~3~CF~3~ (CFC‐113a) (__k__~3~), CClF~2~CClF~2~ (CFC‐114) (__k__~4~), and CCl~2~FCF~3~ (CFC‐114a) (__k__~5~) at 296 K are reported. Rate coe
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