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High-Pressure Stopped-Flow Polymerization for Polypropene- block -poly(ethene- co -propene) Having Controlled Molecular Weight: Synthesis and Characterization

โœ Scribed by Mori, Hideharu; Yamahiro, Mikio; Prokhorov, Valery V.; Nitta, Koh-hei; Terano, Minoru


Book ID
126072271
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
311 KB
Volume
32
Category
Article
ISSN
0024-9297

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Synthesis and basic characteristics of p
โœ Mikio Yamahiro; Hideharu Mori; Koh-hei Nitta; Minoru Terano ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB

A well-defined diblock copolymer, polypropene-block-poly(ethene-co-propene), was synthesized by modified stopped-flow polymerization with an MgCl 2 -supported Ziegler catalyst. The copolymer shows a unimodal gel permeation chromatography (GPC) elution curve without any material in the low molecular