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High-Pressure Solubility Measurement of Solids in Near- and Supercritical Fluids

✍ Scribed by D. Tuma; B. Wagner; G. M. Schneider

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Spectroscopic measurement of solid solub
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## Abstract Different in situ spectroscopic techniques, including infrared, ultraviolet, and fluorescence, were developed to measure the solubility of organic solids in supercritical carbon dioxide (scCO~2~). These techniques are applicable over a wide range of concentrations, as low as 10^βˆ’6^ or 1

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A Response Surface Methodology approach to correlate the solubility data of solids in supercritical Β―uids directly to the pressure and temperature is described. Published data for 2,6dimethylnaphthalene, 2,3-dimethylnaphthalene, phenanthrene and benzoic acid in both supercritical carbon dioxide and

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The possibility of a complete thermodynamic description of the behaviour of dilute solutions on the basis of the Krichevskii function J = (βˆ‚ p/βˆ‚ x) ∞ V,T , which performs well in the near-critical region, is hampered by its weak temperature dependence. A previous determination of the solubility of C