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High-pressure range of the recombination O + O2 → O3

✍ Scribed by A. E. Croce De Cobos; J. Troe

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
487 KB
Volume
16
Category
Article
ISSN
0538-8066

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✦ Synopsis

The recombination reaction 0 + 0, -O3 was studied by laser flash photolysis of pure 0, in the pressure range 3-20 atm, and of N,O-0, mixtures in the bath gases Ar, N,, (CO,, and SF,) in the pressure range 3-200 atm. Fall-off curves of the reaction have been derived. Low-pressure rate coefficients were found to agree well with literature data. A high-pressure rate coefficient of k , = (2.8 ? 1.0) x 10 cm3 molecule ' s I was obtained by extrapolation.

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