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High-pressure NMR kinetics. 47. Solvent-exchange mechanisms of nonaqueous square-planar tetrasolvates: a high-pressure proton NMR investigation

✍ Scribed by Hallinan, Noel.; Besancon, Valerie.; Forster, Marc.; Elbaze, Gilles.; Ducommun, Yves.; Merbach, Andre E.

Book ID: 120457337
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 373 KB
Volume: 30
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00005a043

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## Abstract The water exchange of [V(H~2~O)~6~]Cl~2~ in aqueous solution has been studied as a function of temperature and pressure (up to 250 MPa), by measuring the ^17^O‐FT‐NMR. line‐widths of the free water resonance at 8.13 MHz. The kinetic parameters obtained are __K__ = 87±4 s^−1^, __ΔH__^\*^