In order to calculate some kinetic parameters, such as the reactivity ratios, of the system ␣-methylstyrene-methyl methacrylate, the bulk copolymerization of these two monomers with azobis isobutironitrile (AIBN) as a radical initiator was studied. Experiments were performed at the various temperatu
High-Pressure Kinetics of Oxidative Copolymerization of Styrene with α-Methylstyrene
✍ Scribed by Priyadarsi De; D. N. Sathyanarayana
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 129 KB
- Volume
- 203
- Category
- Article
- ISSN
- 1022-1352
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## Abstract Terpolymers formed from styrene, α‐methylstyrene (AMS), and acrylonitrile (AN) were prepared in different proportions. According to the reaction conditions, the terpolymers presented random sequence distributions. AMS, because of steric hindrance, presented a high degree of instability,