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High pressure fugacity coefficients from equilibria of simple gases and polar liquids

✍ Scribed by R. De Santis; L. Marrelli; M. Sandulli


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
270 KB
Volume
30
Category
Article
ISSN
0009-2509

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✦ Synopsis


An equation of state for mixtures proposed by De Santis, Breedveld and Prausnitz was used to predict the fugacity coefficients in binary gaseous mixtures containing a polar and a simple component. The model has been shown to be sufficiently valid by comparison with experimental fugacity coefficients derived from gas-liquid water equilibria. Special attention has been given to the possibility of systematic experimental errors and their relevance to the validation of the equations.