𝔖 Bobbio Scriptorium
✦   LIBER   ✦

High-Pressure Carbonylation of Metal-Coordinated Carbenes and Hydrogenolysis of the Ketene Complexes

✍ Scribed by Dr. Wolfgang A. Herrmann; Johann Plank


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
239 KB
Volume
17
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Carbonylation of Transition-Metal Carbyn
✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 141 KB πŸ‘ 1 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre

Structure and Bonding of Low-Valent (Fis
✍ Sergei F. Vyboishchikov; Gernot Frenking πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 266 KB

Quantum mechanical ab initio calculations are reported at the MP2 level of theory with effective core potentials for the heavy atoms of the low-valent carbene complexes [(CO) 5 WCH 2 ] (1), [(CO) 5 WCF 2 ] (2), [(CO) 5 WCHF] (3), and [(CO) 5 WCH-(OH)] (4), and for the high-valent carbene complexes [