High-Pressure Carbonylation of Metal-Coordinated Carbenes and Hydrogenolysis of the Ketene Complexes
β Scribed by Dr. Wolfgang A. Herrmann; Johann Plank
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 239 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and β30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre
Quantum mechanical ab initio calculations are reported at the MP2 level of theory with effective core potentials for the heavy atoms of the low-valent carbene complexes [(CO) 5 WCH 2 ] (1), [(CO) 5 WCF 2 ] (2), [(CO) 5 WCHF] (3), and [(CO) 5 WCH-(OH)] (4), and for the high-valent carbene complexes [