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High-pressure (4+2)cycloaddition of 1-methoxybuta-1,3-diene to α-amino aldehydes. Influence of n-protecting groups on asymmetric induction

✍ Scribed by Janusz Jurczak; Adam Gołebiowski; Jerzy Raczko


Book ID
104217686
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
229 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


The stereochemistry of the high-pressure (4+2)cycloaddition


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✍ Janusz Jurczak; Tomasz Bauer; Sławomir Jarosz 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 237 KB

The high-pressure cycloaddition of 1:2,3:4-di-0-isopropyIidene-0(\*2-galactopyra-) . It is noteworthy that the specific rotation of diastereoisomer 2 with opposite configuration at c-6 was [MID-81°(cl,CHC13). w