High‐pressure cycloaddition of 3,4‐dimethoxyfuran with 1,4‐benzoquinone, toluquinone and 2,3‐dimethoxy‐1,4‐benzoquinone show, at 7 kbar and room temperature, prevailing formation of __endo__‐isomers. Raising pressure (or temperature) results in a surprising increase of the __exo__‐isomer. By catalyt
✦ LIBER ✦
High pressure [4 + 2] cycloaddition reactions of 3,4-dimethoxyfuran with dichloromaleic anhydride and with cyclopropane derivatives
✍ Scribed by Matsumoto, Kiyoshi; Ikemi, Yukio; Hashimoto, Shiro; Lee, H. S.; Okamoto, Yoshiyuki
- Book ID
- 126111263
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 263 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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## Abstract As an active diene (more active than furan itself), 3,4‐dimethoxyfuran (**1**) affords with many dienophiles the respective cycloadducts in a high yield [2]. It has recently been found that under thermal conditions **1** easily reacts with maleic anhydride and its monomethyl derivative,
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