High Pressure 17O-FT-NMR. Evidence for the Associative Nature of Substitution Reactions on Mn2+ in Water

High-Pressure 17O-NMR. Study of Vanadium

High-Pressure 17O-NMR. Study of Vanadium (II) in Water: A Second Example of an Associative Interchange Mechanism (Ia) for Solvent Exchange on an Octahedral Divalent Transition-Metal Ion

✍ Yves Ducommun; Donald Zbinden; André E. Murbach 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 312 KB 👁 1 views

## Abstract The water exchange of [V(H~2~O)~6~]Cl~2~ in aqueous solution has been studied as a function of temperature and pressure (up to 250 MPa), by measuring the ^17^O‐FT‐NMR. line‐widths of the free water resonance at 8.13 MHz. The kinetic parameters obtained are __K__ = 87±4 s^−1^, __ΔH__^\*^