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High photoreduction yield of Eu3+ to Eu2+ in alcoholic solutions and its wavelength dependence

✍ Scribed by Kusaba, Mitsuhiro; Nakashima, Nobuaki; Kawamura, Wataru; Izawa, Yasukazu; Yamanaka, Chiyoe


Book ID
121780821
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
193 KB
Volume
192
Category
Article
ISSN
0925-8388

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Higher yield of photoreduction from Eu3+
✍ Mitsuhiro Kusaba; Nobuaki Nakashima; Wataru Kawamura; Yasukazu Izawa; Chiyoe Yam πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 368 KB

We have found that the photoreduction yield from Eu3+ to Eu\*+ depends on excitation wavelength within a single chargetransfer band. The quantum yields 4 were 0.12 k 0.02 (at I93 nm) and 0.06 + 0.0 1 (at 222 nm) in aqueous solution, and 0.42 t 0.07 (at 222 nm) and 0.35 kO.06 (at 248 nm) in methanol