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High performance liquid chromatography (HPLC) interfaced with an electron paramagnetic resonance spectrometer; its application in the determination of micro quantities of metalloporphyrins

✍ Scribed by Evans, J. C. ;Jackson, A. H. ;Rao, K. R. N. ;Rowlands, C. C.


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
164 KB
Volume
8
Category
Article
ISSN
0935-6304

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✦ Synopsis


as Cu2+ orV02+. Electron paramagnetic resonance (EPR) merely as a detector has been used previously to detect certain spin trapped amino acid radicals [2], the eluting components from the column passing through a capillary tube within the EPR cavity. We report the construction of a flow cell which has enabled us to use the spectrometer as a specific detector and for obtaining EPR spectra of components.